Precision pressed glass object, glass, method of preparing glass

ABSTRACT

Glass objects, lenses in particular, can be pressed with precision from a glass which contains 45-55 mol. % P2O5, 15-40 mol. % BaO, 5-15 mol. % Li2O, 5-35 mol. % PbO, 0-2 mol. % Al2O3 and 0-6 mol. % F.

This is a continuation-in-part of application Ser. No. 119,324, filed Feb. 7, 1980.

The invention relates to precision pressed glass objects, to glass and to a method of preparing that glass.

The invention provides precision pressed objects made of glass, lenses in particular, both spherical and aspherical lenses. Precision pressed is here understood to mean that, after pressing, without further aftertreatment, the lens does not deviate at any single point of its surface by more than 0.5 micrometers from the desired curvature, the surface roughness being less than 0.02 micrometers.

Lenses are used in a great variety of products, including film cameras, and equipment for reading information with laser beams.

No glasses are known from which objects can be pressed with such precision.

The invention provides a glass from which objects can be pressed with the above-defined precision.

The precision pressed objects of glass and the glass according to the invention are characterized in that the glass contains 45-55 mol. % P₂ O₅, 15-40 mol. % BaO, 5-35 mol. % PbO, 5-15 mol. % Li₂ O, 0-2 mol. % Al₂ O₃ and 0-6 mol. % F in the form of fluoride, wherein up to 25% of the BaO may be replaced by an equimolar quantity of one or more of the oxides CaO, MgO and SrO, and up to 25% of the Li₂ O may be replaced by an equimolar quantity of one or more other alkali metal oxides.

Glasses intended for the precision pressing of lenses must satisfy several requirements. In order to be pressable, the glass must be sufficiently soft. In the circumstances prevailing during pressing, the glass must not crystallize, that is to say it must be stable. For the practical application of the glass it is extremely important that the glass should be sufficiently resistant to atmospheric influences (corrosion resistant).

Furthermore, colourless glass is generally preferred for lenses.

A glass is known from U.S. Pat. No. 3,281,253 which is prepared from aluminium metaphosphate, and alkali metal metaphosphate, an alkaline earth metal metaphosphate and lead metaphosphate. This glass is used for lens systems. The known glass does not satisfy the above-defined requirements as regards composition. In addition, no indication is given how the lens systems are produced.

The invention is based on the recognition of the fact that the above-mentioned requirements imposed on glasses intended for precision pressing can only be optimally satisfied by the choice of one specific alkaline earth metal oxide, namely barium oxide, by the choice of a specific alkali metal oxide, namely lithium oxide, and by the choice of specific range for the composition of the glass.

Very satisfactory results as regards the abovementioned properties have been obtained with the following glasses: 45-55 mol. % (preferably 46-52 mol. %) P₂ O₅, 15-35 mol. % (preferably 18-22 mol. %) BaO, 8.5-11.5 mol % (preferably 9-11 mol. %) Li₂ O, 9-22 mol. % (preferably 18-22 mol. %) PbO, 0-2 mol. % Al₂ O₃ and 0-6 mol. % F in the form of fluoride.

The glasses according to the invention are colourless, properly pressable (not too hard) and have a corrosion resistance better than class 1 (that is to say, after having been stored for 2 weeks at 50° C. in a relative humidity of 99% the glasses according to the invention were free from stains). In addition, the glasses according to the invention are stable, that is to say they do not tend to crystallize during their preparation or during their use for the pressing of lenses.

The P₂ O₅ content of the glass according to the invention was chosen between 45 and 55 mol. %. When the P₂ O₅ content is below 45 mol. % the glass becomes too hard to allow pressing and is not sufficiently stable. When the P₂ O₅ content exceeds 55 mol. %, the corrosion resistance is inssuficient.

The glass according to the invention contains 15-40 mol. % BaO as the alkaline earth metal oxide. Not more than 25% of the BaO may be replaced by one or more other alkaline earth metal oxides. Higher contents of CaO and SrO cause crystallization; higher contents of MgO affect the corrosion resistance negatively.

A BaO content below 15 mol. % results in an inadequate corrosion resistance. A BaO content of more than 40 mol. % diminishes the stability and reduces the pressability.

The glass according to the invention contains 5-15 mol. % Li₂ O. When the Li₂ O content is less than 5 mol. %, the pressability and the stability are inadequate. When the quantity of Li₂ O exceeds 15 mol. %, the corrosion-resistance is too low. Up to 25% of the Li₂ O may be replaced by one or more other alkali metal oxides. Inherently, such a replacement results in a reduced corrosion-resistance.

As in the case of the known glasses, the glass according to the invention contains PbO. The limits for the PbO content have been determined on the base of tests: a PbO content below 5 mol. % results in an insufficient pressability and too low a stability. A content of more than 35 mol. % reduces both the corrosion-resistance and the stability.

The glass according to the invention may comprise the customary glass additives. More particularly, the glass may contain 0-2 mol. % Al₂ O₃ (to improve the stability) and 0-6 mol. % F as fluoride (to improve the pressability).

The glasses according to the invention may be produced in accordance with any customary technique for preparing glass. The carbonates, nitrates, metaphosphates, etc. of the above-mentioned cations may be used as the starting material.

A method of producing the precision pressed object from glass according to the invention will now be explained with reference to the accompanying drawing. In this drawing:

FIG. 1 shows a device for carrying out such a method and

FIG. 2 shows a precision pressed object according to the invention.

The device shown in FIG. 1 for the precision pressing of an object of glass consists of a lower die (2) and an upper die (3). The dies have been provided with thermocouples (4) which are connected to a heating element (1) via a control unit, not shown. The precision pressed object is denoted by (5).

The object according to the invention can be produced with the device shown in FIG. 1 in the following manner.

A precision-ground cube produced from glass according to the invention is positioned on a carrier (6). The cube need not have been X polished. The cube is preheated in an oven to, for example, 20°-60° C. above the American softening point, a polishing effect of the cube surface then being obtained. In the meantime the dies of the device, shown in FIG. 1 have been pre-heated to a temperature of 10°-40° C. above the American softening point of the glass used. Thereafter the pre-heated glass cube and carrier 6 are together positioned between the dies 2 and 3. The dies are then closed. After opening of the dies an object is obtained as shown in FIG. 2. When this method starts from a cube produced from glass according to the invention, an object is obtained that has been pressed with the above-defined precision.

EXAMPLE

Seven glasses having the composition shown in Table A were prepared by fusing appropriate mixtures of starting materials. The compositions were calculated with respect to the quantities of starting materials used. All glasses satisfied the above-defined requirements: they are sufficiently corrosion resistant, have no tendency to crystallize and are sufficiently soft for pressing operations. The glasses are colourless.

By means of the device shown in FIG. 1, lenses were pressed from the glasses numbers 6 and 7. The dies were made of chromium-nickel steel. Pressing was carriedout at a temperature of 440° C.

                  TABLE A                                                          ______________________________________                                         (mol. %)                                                                       No.     1       2       3    4     5    6     7                                ______________________________________                                         P.sub.2 O.sub.5                                                                         45     45      49   50    55   50    46,8                             BaO      22     33      19,6 30    27   20    18,8                             Li.sub.2 O                                                                              11     11       9,8 10     9   10     9,3                             PbO      22     11      19,6 10     9   20    18,8                             Al.sub.2 O.sub.3                                                                        --     --       0,5 --    --   --     0,9                             F        --     --       1,5 --    --   --     5,4                             American                                                                       softening                                                                      points °C.                                                                       420    390     425  435   430  405   409                              ______________________________________                                    

The American softening point is the temperature at which the viscosity is 10⁷.6 poise. 

What is claimed is:
 1. A method of preparing glass containing P₂ O₅, PbO and BaO by fusing together starting materials of said oxides, characterized in that a glass is prepared which consists essentially of 45-55 mol. % P₂ O₅, 15-40 mol. % BaO, 5-35 mol. % PbO, 5-15 mol. % Li₂ O, 0-2 mol. % Al₂ O₃ and 0-6 mol. % F, wherein up to 25% of the BaO may be replaced by an equimolar quantity of one or more of the oxides CaO, MgO, and SrO, and up to 25% of the Li₂ O may be replaced by an equimolar quantity of one or more other alkali metal oxides. 